Chad Cameron is children's, editorial, and advertising illustrator. His website is very sweet, as are his illustrations. The graphics and layout are simple, but very effective.
Bert Spangemacher is a fashion and beauty photographer who lives in NYC. It's a relatively simple site but I like the details; the way the images scroll, how the title appears about when you hover over an image, the format of the larger image. Also I like his "about" section. It is not even really a page, just a bar that fades over whatever page you are on; makes it easy to get back to what you were looking at before. The photography itself is interesting as well.